Joseph M. Tanski

Associate Professor of Chemistry

Vassar College

Publications and Talks

(undergraduate collaborators underlined)

64.  “Synthesis and crystal structures of Ni(II), Cu(II) and μ-oxo-Fe(III) complexes of a salen type ligand: Mononuclear versus multinuclear complex formation;” Rusere, L. N.; Shalumova, T.;  Tanski, J. M.; Tyler, L. A. Polyhedron, 2009, in press.

63.  “Triamidoamine-supported zirconium complexes in the catalytic dehydrocoupling of 1,2-bisphosphinobenzene and –ethane;” Ghebreab, M. B.; Shalumova, T.; Tanski, J. M.; Waterman, R. Polyhedron, 2009, in press.

62. “Dimethyl(2,2':6',2''-terpyridine-κ3N,N',N'')zinc(II);” Shalumova, T.; Tanski J. M. Acta Cryst. 2009, E 65, m1325.

61. “{2-[Bis(3-methyl-1H-indol-2-yl)methyl]phenolato-κO}dimethyl(tetrahydrofuran-κO)aluminium(III);” Eisenberg, A. C.; Tanski J. M.; Getzler Y. D. Y. L. Acta Cryst. 2009, E 65, m1353.

60.  “Chiral-at-metal tetrahydrosalen complexes of resolved titanium(IV) sec-butoxides:  Ligand wrapping and multiple asymmetric catalytic induction;” MacMillan, S. N.; Jung, C. F.; Shalumova, T.; Tanski, J. M. Inorg. Chim. Acta 2009, 362, 3134-3146.

59.  “Design of nickel chelates of tetradentate N-heterocyclic carbenes with subdued cytotoxicity;” Ray, S.; Asthana, J.; Tanski, J. M.; Shaikh, M. M.; Panda, D.; Ghosh, P. J. Organomet. Chem. 2009, 694, 2328-2335.

58.  “Synthesis of platinum(II) cyclometallated compounds derived from imines containing pyridyl or pyrimidyl groups;” Crespo, M.; Anderson, C. M.; Tanski, J. M. Can. J. Chem. 2009, 87,  80-87.

57.  “General Preparation of (N3N)ZrX (N3N = N(CH2CH2NSiMe3)33–) Complexes from a Hydride Surrogate;” Roering, A. J.; Maddox, A. F.; Elrod, L. T.; Chan, S. M.; Ghebreab, M. B.; Donovan, K. L.; Davidson, J. J.; Hughes, R. P.; Shalumova, T.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. Organometallics 2009, 28, 573-581.

56.  “trans-Tetraiodidobis(tri-p-tolylphosphine oxide-κO)tin(IV);”  Hitosugi-Levesque, M.; Tanski, J. M. Acta Cryst. 2008, E 64, m1107/1-m1107/8.

55.  “Syntheses and crystal structures of mono-, di- and trinuclear cobalt complexes of a salen type ligand;”  Welby, J.; Rusere, L. N.; Tanski, J. M.; Tyler, L. A. Inorg. Chim. Acta 2009, 362, 1405-1441.

54.  “Bis{4,4',6,6'-tetrachloro-2,2'-[trans-(R,R)-cyclohexane-1,2-diylbis(iminomethylene)]diphenolato-κ4O,N,N',O'}zirconium(IV);”  Shalumova, T.; Tanski, J. M. Acta Cryst. 2008, E 64, m1029/1-m1029/13.

53.  “Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O']tin(IV) chloroform solvate;” Caldwell, A. L.; Tanski, J. M. Acta Cryst. 2008, E 64, m894/1-m894/9.

52.  “Designing ionic liquids with boron cluster anions: alkylpyridinium and imidazolium [nido-C2B9H11] and [closo-CB11H12] carborane salts,”  Dymon, J.; Wibby, R.; Kleingardner, J.; Tanski, J. M.; Guzei, I. A.; Holbrey, J. D.; Larsen, A. S.  J. Chem. Soc., Dalton Trans. 2008, 22, 2999-3006. 

51.  “Synthesis and Optical Activity Analysis of Chiral Titanium(IV) sec-Butoxide and its Group IV Analogues,” MacMillan, S. N.; Ludford, K. T.; Tanski,J. M. Tetrahedron: Asymmetry 2008, 19, 543-548.

50.  “X-ray crystallographic and DFT structural analysis of chiral-at-metal titanium-salcean complexes,” Tanski, J. M.; MacMillan, S. N.; Jung, C. F. Abstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008.

49.  “{N,N-Bis[2-(trimethylsilylamino)ethyl]-N'-(trimethylsilyl)ethane-1,2-diaminato(3-)-k4N}methylzirconium(IV);” MacMillan, S. N.; Tanski, J. M.; Waterman, R. Acta Cryst. 2008, E 64, m477/1-m477/9.

48.  “Reractivity of the Ni->B Dative s-Bond  in the Nickel Boratrane Compounds [k4-B(mimtBu)3]NiX (X = Cl, OAc, NCS, N3­):  Synthesis of a Series of B-Functionalized Tris(2-mercapto-1-t-butylimidazolyl)borato Complexes, [YtmtBu]NiZ;”  Pang, K.; Tanski, J. M.; Parkin, G. Chem. Commun. 2008, 1008-1010.

47.  “Mechanistic Variety in Zirconium-Catalyzed Bond-Forming Reaction of Arsines;” Roering, A. J.; Davidson, J. J.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. J. Chem. Soc., Dalton Trans. 2008, 33, 4488-4498.

46.  “Synthesis, characterization, and in vitro evaluation of a potentially selective anticancer, mixed-metal [ruthenium(III)-platinum(II)] trimer;” Herman, A; Tanski, J. M.; Tibbetts, M. F.; Anderson, C. Inorg. Chem. 2008, 47, 274-280.

45.  “Insertion of Benzylisocyanide into a Zr–P bond and Rearrangement.  Atom-Economical Synthesis of a Phosphaalkene,” MacMillan, S. N.; Tanski,J, M.; Waterman, R. Chem. Commun. 2007, 4172-4174.

44.  “Synthesis, molecular structure (X-ray and DFT) and solution behavior of titanium 4-acyl-5-pyrazolonates.  Correlations with related antitumor beta-diketonato derivatives,”  Caruso, F.; Pettinari, C.; Marchetti, F.; Natanti, P.; Phillips, C.; Tanski, J.; Rossi, M. Inorg. Chem. 2007, 46, 7553-7560.

43.  “Zirconium-Catalyzed Heterodehydrocoupling of Primary Phosphines with Silanes and Germanes,”Roering, A. J.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. Inorg. Chem. 2007, 46, 6855-6857.

42.  “A Practical and Efficient Synthesis of 1-Substituted m-Terphenyls;” Kehlbeck, J. D.; Dimise, E.  J.; Sparks, S. M.; Ferrara, S.; Tanski, J. M.; Anderson, C., Synthesis 2007, 13,1979–1983.

41. “Structural Analysis of Bisphenol-A and its Methylene, Sulfur, and Oxygen Bridged Bisphenol Analogs,” Lim, C. F.; Tanski, J. M. J. Chem. Cryst. 2007, 37, 587-595.

 

40.  Factors Influencing Coordination versus Oxidative Addition of C-H Bonds to Molybdenum and Tungsten: Structural and Spectroscopic Evidence That the Calixarene Framework Promotes C-H Bond Activation,” Buccella, D.; Tanski, J. M.; Parkin, G. Organometallics 2007, 26, 3275-3278.

 

39.  Synthesis and structural characterization of tris(phenolate)amine complexes of antimony derived from [κ4-N(CH2ArBu2tO)3]Sb,” Kelly, B. V.; Weintrob, E. C.; Buccella, D.; Tanski, J. M.; Parkin, G. Inorg. Chem. Comm. 2007, 10, 699-704.

 

38.  Variations in the coordination environment of Co2+, Cu2+ and Zn2+ complexes prepared from a tridentate (imino)pyridine ligand and their structural comparisons,” Davis, R. N.; Tanski, J. M.; Adrian, J. C.; Tyler, L. A. Inorg. Chim. Acta 2007, 360, 3061-3068.

 

37.  Structural diversity and homochirality in titanium aryloxide metal-organic network materials derived from 4,4'-bisphenols,” Tanski, J. M.; Ludford, K. T.; Lim, C. F. Abstracts of Papers, 232nd ACS National Meeting, San Francisco, CA, United States, Sept. 10-14, 2006.

 

36.  Chiral alkoxides of titanium, zirconium and hafnium: Synthesis, characterization and optical activity analysis,” MacMillan, S. N.; Tanski, J. M. Abstracts of Papers, 232nd ACS National Meeting, San Francisco, CA, United States, Sept. 10-14, 2006.  

 

35.  Reactivity of cyclometallated platinum complexes with chiral ligands;” Anderson, C.; Crespo, M.; Morris, J.; Tanski, J. M. J. Organomet. Chem. 2006, 26, 5647-5653.

 

34.  “C-H versus O-H Bond Cleavage Reactions of Bis(2-hydroxyphenyl)phenylamine, PhN(o-C6H4OH)2: Synthesis and Structural Characterization of Mononuclear and Dinuclear Tungsten Aryloxide Complexes Which Exhibit Bidentate, Tridentate, and Tetradentate Coordination Modes;” Kelly, B. V.; Tanski, J. M.; Janak, K. E.; Parkin, G. Organometallics 2006, 25, 5839-5842.

 

33.   Modular Chelated Palladium Diaminocarbene Complexes: Synthesis, Characterization, and Optimization of Catalytic Suzuki-Miyaura Cross-Coupling Activity by Ligand Modification;” Moncada, A. I.; Manne, S.; Tanski, J. M.; Slaughter, L. M. Organometallics 2006, 25, 491-505.

 

32.  Synthesis, spectroscopy (IR, multinuclear NMR, ESI-MS), diffraction, density functional study and in vitro antiproliferative activity of pyrazole-beta-diketone dihalotin(IV) compounds on 5 melanoma cell lines;” Pettinari, C.; Caruso, F.; Zaffaroni, N.; Villa, R.; Marchetti, F.; Pettinari, R.; Phillips, C.; Tanski, J.; Rossi, M. J. Inorg. Biochem. 2006, 100, 58-69. 

 

31.  Synthesis and structural analysis of Bis(2-hydroxyphenyl) phenylamine, PhN(o-C6H4OH)2: Comparison with Tris(2-hydroxyphenyl)amine N(o-C6H4OH)3;” Kelly, B. V.; Tanski, J. M.; Anzovino, M. B.; Parkin, G. J. Chem.Cryst. 2005, 35, 969-981.

 

30.  Sterically controlled formation of monodentate versus chelating carbene ligands from phenylhydrazine;” Moncada, A. I.; Tanski, J. M.; Slaughter, L. M. J. Organomet. Chem. 2005, 690, 6247-6251.

 

29.  Structure determination of aligned systems by solid-state NMR magic angle spinning methods;” Gross, B. J.; Tanski, J. M.; McDermott, A. E. J. Mag. Res. 2005, 176, 223-233.

 

28.  Multidentate aryloxide and oxo-aryloxide complexes of antimony: synthesis and structural characterization of [κ4-N(o-C6H4O)3]Sb(OSMe2), {{[κ3-N(o-C6H4OH)(o-C6H4O)2]Sb}22-O)}2 and {[κ3-PhN(o-C6H4O)2]Sb}43-O)2;” Tanski, J. M.; Kelly, B. V.; Parkin, G. J. Chem. Soc., Dalton Trans. 2005, 14, 2442-2447.

                 

27.  “Structural Basis for trans-Resveratrol’s Antioxidant Activity: ab-initio Calculations and Crystal and Molecular Structure,” Caruso, F.; Tanski, J.; Villegas-Estrada, A.; Rossi, M. J. Agricult. Food Chem. 2004, 52, 7279–7285.

 

26.  The molecular structure of the tris(2-mercapto-1-toly-limidazolyl)hydroborato zinc(2-mercapto-1-tolylimidazole) complex, {[Tmp-Tol]Zn(mimp-Tol)}[ClO4]: intermolecular N–H···OClO3 versus intramolecular N–H···S hydrogen bonding interactions of the mercaptoimidazole ligand.” Morlok, M. M.; Docrat, A.; Janak, K. E.; Tanski, J. M.; Parkin, G. J. Chem. Soc., Dalton Trans. 2004, 21, 3448-3452.

 

25.  Tin(II) and Lead(II) 4-Acyl-5-pyrazolonates: Synthesis, Spectroscopic (IR, 1H, 13C and 119Sn NMR, 119Sn Mössbauer and ESI-MS) and X-ray Structural Characterization,” Pettinari, C.; Marchetti, F.;  Pettinari, R.;  Cingolani, A.;  Rivarola, E.; Phillips, C.;  Tanski, J.;  Rossi,  M.; Caruso, F. Eur. J. Inorg Chem. 2004, 17, 3484-3497.

 

24. “Cobalt Tris(mercaptoimidazolyl)borate Complexes: Synthetic Studies and the Structure of the First Cobaltaboratrane,” Mihalcik, D. J.; White, J. L.; Tanski, J. M.; Zakharov, L. N.; Yap, G. P. A.; Incarvito, C. D.; Rheingold A. L.; Rabinovich, D. J. Chem. Soc., Dalton Trans. 2004, 10, 1626-1634.

 

23. "Poly(mercaptoimidazolyl)borate chemistry and the predominance of κ3-S,S,H over κ2-S,S or κ3-S,S,S coordination modes:  unexpected formation of square pyramidal Ni(II) complexes"  Alvarez, H. M.; Tanski, J. M.; Rabinovich, D. Polyhedron 2004, 23, 395-403.

 

22. “Homoleptic Group 12 Metal Bis(mercaptoimidazolyl)borate Complexes M(BmR)2 (M = Zn, Cd, Hg): Synthesis, Characterization, and Structural Relevance to Metallothioneins,” Alvarez, H. M.; Tran, T. B.; Richter, M. A.; Alyounes, D. M.; Tanski, J. M.; Krawiec, M.; Rabinovich, D. Inorg. Chem. 2003, 42, 2149-2156.

 

21. “Antitumor Activity of the Mixed Phosphine Gold Species Chlorotriphenylphosphine-1,3-bis(diphenylphosphino)propanegold(I),” Caruso, F.; Rossi, M.; Tanski, J.; Pettinari, C.; Marchetti, F. J. Med. Chem. 2003, 46, 1737-1742.

 

20. “Synthesis and structural characterization of 2-mercapto-1-tert-butylimidazole and its group 12 metal derivatives (HmimtBu)2MBr2 (M = Zn, Cd, Hg),”  White, J. L.; Tanski, J. M.; Churchill, D. G.; Rheingold, A. L.; Rabinovich, D. J. Chem. Cryst. 2003, 33, 437-445.

 

19. “Synthesis and Characterization of Some Chloro, Methoxy and Mercapto Derivatives of [Ru(η2-2,2'-bipyridine )3]+2 2 PF6-: Crystal and Molecular Structures of [Ru(η-2,2'-bipyridine )22-4,4'-X2-2,2'-bipyridine)]+2 2 PF6- (X = Cl, OMe),” Hansen, L. E.; Glowacki, E. R.; Arnold, D. L.; Bernt, G. J.; Chi, B.; Fites, R. J.; Freeburg, R. A.; Rothschild, R. F. N.; Krieg, M, C.; Howard, W. A.; Tanski, J. M.; Inorg. Chim. Acta 2003, 348, 91-96.

 

18. “(4-Acyl-5-pyrazolonato)Titanium Derivatives: Oligomerization, Hydrolysis, Voltammetry and DFT Study,” Caruso, F.; Massa, L.; Gindulyte, A.; Pettinari, C.; Marchetti, F.; Pettinari, R.; Ricciutelli, M.; Costamagna, J.; Canales, J. C.; Tanski, J. M.; Rossi, M. Eur. J. Inorg Chem. 2003, 17, 3221-3232.

 

17. “Tantalum Amido and Imido Complexes Supported by Tris [(2–indolyl)methyl] amine, a Tetradentate Trianionic Ligand with Reduced π–Donor Properties,” Tanski, J. M.; Parkin, G. Inorg. Chem. 2003, 42, 264-266.

 

16. “Synthesis and Structure of [pzBut2]Mo(PMe3)4H, an η2-3,5-di-t-butylpyrazolyl Molybdenum Complex,” Zhu, G.; Tanski, J. M.; Parkin, G. Polyhedron 2003, 22, 199-203.

 

15. “Synthesis and Structural Characterization of 2,5-Diphenylpyrrolyl Complexes of Zinc, [pyr2,5-Ph2]2Zn(THF) and

[pyr2,5-Ph2]Zn(THF)23-O)Zn[pyr2,5-Ph2]}2:   A Zinc Oxo Complex with a Planar μ3-Oxo Bridge,” Zhu, G.; Tanski, J. M.; Parkin, G. J. Chem. Cryst. 2002, 32, 469-475.

 

14. “The Reactivity of Mo(PMe3)6 towards Nitrogen Heterocycles: Transformations Relevant to Hydrodenitrification,” Zhu, G.; Tanski, J. M.; Churchill, D. G.; Janak, K.; Parkin, G. J. Am. Chem. Soc. 2002, 124, 13658-13659.

 

13. “The Synthesis and Molecular Structures of 2,5-Diarylpyrroles, [pyrAr2]H (Ar = Ph, 2,4-Xyl),” Tanski, J. M.; Parkin, G. J. Chem. Cryst. 2002, 32, 185-190.

 

12. “The Synthesis and Structure of Antimony Glycolate and Catecholate Compounds of Relevance to Catalytic Polyesterification Reactions,” Biros, S. M.; Bridgewater , B. M.; Villegas-Estrada, A.; Tanski, J. M.; Parkin, G. Inorg. Chem. 2002, 41, 4051-4057.

11. “Bulky Tris(mercaptoimidazolyl)borates: Synthesis and Molecular Structures of the Group 12 Complexes (TmtBu)MBr (M=Zn, Cd, Hg),” White, J. L.; Tanski, J. M.; Rabinovich, D. J. Chem. Soc., Dalton Trans. 2002, 2987-2991.

 

10. “Thiophene and Butadiene-Thiolate Complexes of Molybdenum: A New Mechanism for C-S Cleavage and Hydrogenation During Hydrodesulfurization,” Janak, K. E.; Tanski, J. M.; Churchill, D. G.; Parkin, G. J. Am. Chem. Soc. 2002, 124, 4182-4183.

 

9. “Synthesis and Structures of Zirconium-Pyrrolyl Complexes: A Computational Analysis of the Factors that Influence the Coordination Modes of Pyrrolyl Ligands,” Tanski, J. M.; Parkin, G. Organometallics 2002, 21, 587-589.

 

8. “Towards the Total Synthesis of Guanacastepene: Remarkable Stereoselectivity in the Substrate Controlled Assembly of the C8 Quaternary Center,” Dudley, G. B.; Tan, D. S.; Guncheol, K.; Tanski, J. M.; Danishefsky, S. J. Tetrahedron Lett. 2001, 42, 6789-6791.

 

7. “Covalent Titanium Aryldioxy One-, Two- and Three-Dimensional Networks and Their Examination as Ziegler-Natta Catalysts,” Tanski, J. M.; Wolczanski, P. T. Inorg. Chem. 2001, 40, 2026-2033.

 

6. “Covalent Vanadium(III) Two-Dimensional Network and Vanadyl Chains Linked by Aryloxides,” Tanski, J. M.; Wolczanski, P. T. Inorg. Chem. 2001, 40, 346-353.

 

5. “Covalent Metal-Organic Networks: Pyridines Induce Two-Dimensional Oligomerization of (μ-OC6H4O)2Mpy2 (M=Ti, V, Zr),” Tanski, J. M.; Vaid, T. P.; Lobkovsky, E. B.; Wolczanski, P. T. Inorg. Chem. 2000, 39, 4756-4765.

 

4. “Covalent Titanium(IV)-Aryloxide Network Materials: 4,4’-Biphenoxide 3D and Polyphenolic 2D Motifs,” Tanski, J. M.; Lobkovsky, E. B.; Wolczanski, P. T. J. Solid State Chem. 2000, 152, 130-140.

 

3. “Synthesis, Structure and Antitumor Activity of a Novel Tetranuclear Titanium Complex,” Caruso, F.; Rossi, M.; Tanski, J.; Sartori, R.; Sariego, R.; Moya, S.; Diez, S.; Navarrete, E.; Cingolani, A.; Marchetti, F.; Pettinari, C. J. Med. Chem. 2000, 43, 3665-3670.

 

2. “Covalent Three-Dimensional Titanium(IV)-Aryloxide Networks,” Vaid, T. P.; Tanski, J. M.; Pette, J. M.; Lobkovsky, E. B.; Wolczanski, P. T. Inorg. Chem. 1999, 38, 3394-3405.

 

1. “Tin(IV) and organotin(IV) derivatives of novel β-diketones I.  Dialkyltin(IV) complexes of 1-phenyl-3-methyl-4-R’(C=O)-pyrazol-5-one (R’= CCl3, OCH3, OC2H5, O-i-C3H7, OC7H7). Crystal and molecular structure of trans-dimethylbis[1-phenyl-3-methyl-4-i-propoxycarbonyl-pyrazolone-5-ato]tin(IV),” Pettinari, C.; Marchetti, F.; Gregori, A.; Cingolani, A.; Tanski, J.; Rossi, M.; Caruso, F. Inorg. Chim. Acta 1998, 257, 37-48.

 

 

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